Search results for "binary [neutron star]"
showing 10 items of 544 documents
Surface-directed spinodal decomposition: modelling and numerical simulations
1997
We critically review the modelling and simulations of surface-directed spinodal decomposition, namely, the dynamics of phase separation of a critical or near-critical binary mixture in the presence of a surface with a preferential attraction for one of the components of the mixture.
Surface order in body-centered cubic alloys
1993
Free (100)-surfaces of body-centered cubic binary alloys are studied in a parameter range where the bulk turns from the ordered B2-phase to the disordered A2-phase. A model is chosen that describes iron-aluminium alloys in a fairly realistic way. Mean field treatments and Monte Carlo investigations both show that under certain circumstances the surface remains ordered far above the bulk disordering temperatureT c, though the surface order parameter and the surface susceptibility exhibit a singularity atT c with critical exponents characteristic for the ordinary transition. One finds, that if the surface is nonstoechiometric and different layers are not equivalent with respect to perfect bul…
Order and Disorder Phenomena at Surfaces of Binary Alloys
2000
We present recent Monte Carlo results on surfaces of bcc-structured binary alloys which undergo an order-disorder phase transformation in the bulk. In particular, we discuss surface order and surface induced disorder at the bulk transition between the ordered (DO3) phase and the disordered (A2) phase. An intricate interplay between different ordering and segregation phenomena leads to a complex surface behavior, which depends on the orientation of the surface under consideration.
Bridging scales with thermodynamics: from nano to macro
2014
We have recently developed a method to calculate thermodynamic properties of macroscopic systems by extrapolating properties of systems of molecular dimensions. Appropriate scaling laws for small systems were derived using the method for small systems thermodynamics of Hill, considering surface and nook energies in small systems of varying sizes. Given certain conditions, Hill's method provides the same systematic basis for small systems as conventional thermodynamics does for large systems. We show how the method can be used to compute thermodynamic data for the macroscopic limit from knowledge of fluctuations in the small system. The rapid and precise method offers an alternative to curre…
On the Neron-Severi group of surfaces with many lines
2008
For a binary quartic form $\phi$ without multiple factors, we classify the quartic K3 surfaces $\phi(x,y)=\phi(z,t)$ whose Neron-Severi group is (rationally) generated by lines. For generic binary forms $\phi$, $\psi$ of prime degree without multiple factors, we prove that the Neron-Severi group of the surface $\phi(x,y)=\psi(z,t)$ is rationally generated by lines.
Spinodal decomposition in thin films: Molecular-dynamics simulations of a binary Lennard-Jones fluid mixture
2005
We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A) with the same strength. The pair-wise interactions between the particles is modeled by the Lennard-Jones potential, with symmetric parameters that lead to a miscibility gap in the bulk. In the thin-film geometry, an interesting interplay occurs between surface enrichment and phase separation. We study the evolution of a mixture with equal amounts of A and B, which is rendered unstable by a temperature quench. We find that A-rich surface enrichment layers fo…
On the significance of molecular surfaces and thermodynamic interactions for the excess viscosities of liquid mixtures
1994
The viscosities η of homogeneous binary mixtures of liquids are usually approximated as In η = ϕ1 In η1 + ϕ2 In η2 where ϕi and ηi are the volume fractions and the viscosities, resp., of the i-th pure substance; the behavior of real systems is then discussed in terms of Δ In η, the deviations from the above reference behavior. Here a semi-empirical approach is presented according to which volume fractions are replaced by the surface fractions Ωi to create a more realistic reference state, and the thermodynamic interaction parameter g is taken into account. The new equation reads (expressing it for practical purposes still in the terms of ϕi) γ is a geometric factor, measuring the difference…
Surface segregation trends in transition metal alloys
2013
In this work, we revisit the problem of predicting the surface segregation trends in binary transition metal alloys from the knowledge of the basic features of the pure component $d$-band electronic structure within tight-binding approximation. In contrast to previous trend studies, the present one includes, within the fourth-moment approximation (FMA) of the tight-binding scheme, both the difference in the average band energies (diagonal disorder) and the difference in the band widths (off-diagonal disorder) of the two components. We show that treating on the same footing these two effects is essential for a correct prediction of surface segregation. The presented study, giving a natural l…
A proposed equation of correlation for the study of thermodynamic properties (density, viscosity, surface tension and refractive index) of liquid bin…
2009
Abstract The literature on the physicochemical properties of liquid binary mixtures shows that most such systems exhibit nonlinear behavior. As a result, rigorous data and equations capable of affording a reliable estimate of the behavior of such mixtures are needed. The present study offers an equation of correlation providing a reliable estimation of the properties (density, viscosity, surface tension and refractive index) of binary mixtures of liquids as a function of mole fraction. In order to assess the validity of the proposed equation, the latter has been applied to reference binary mixtures, and comparisons have been made of the experimental values of the studied magnitudes versus t…
Densities, Refractive Indices, and Excess Molar Volumes of Binary and Ternary Systems Containing Isobutyl Alcohol, Ethanol, 2-Methylpentane, and Meth…
2000
This paper reports experimental densities and refractive indices of binary and ternary systems containing isobutyl alcohol, ethanol, 2-methylpentane, and methyl tert-butyl ether over the whole composition range of mixtures at 298.15 K and atmospheric pressure. From these data, excess molar volumes VE have been calculated. These results are fitted to the Redlich−Kister and Cibulka polynomial equations to derive the binary and ternary coefficients, respectively.